I am amazed with recent reading I've been doing as to all the factors pertaining to DNAPL migration in the sub-surface. 95% of those factors have never been discussed at public UPAC or CPAC, TAG or TRAC meetings. This is not by accident. Most of these factors including density, viscosity, wettability, stratigraphic slopes, pore sizes, solubility, volatility, groundwater velocity etc. have been known for decades . More recently I have seen technical reports advising that potential and probable lateral (horizontal) migration of free phase DNAPL has been seriously underestimated for decades. Again the factors affecting horizontal migration are many and include of course the volume of DNAPL released at the surface or from shallow lagoons (such as Uniroyal Chemical). Another obvious factor is how much of this DNAPL is able to penetrate through aquifers and or aquitards vertically. Clearly if the aquitards (clay/silt) are discontinuous or have cracks and "windows" in them then the vertical penetration increases.
A couple of recent reports state that horizontal migration of DNAPL has been found at both 650 metres in one site from the source area and 750 metres at another site. Now two things seem obvious to me and that is the overall ongoing slope of the stratigraphic unit that the DNAPL is moving on as well as the large amount of free phase DNAPL released to the subsurface in order to "push" the DNAPL that far from its' source. I certainly can understand the unlikelihood of these distances from source being anywhere near the norm.
The other interesting tidbit I've begun to understand is how often for example chlorinated solvent sites with groundwater concentrations exceeding 1% still remain without the subsurface DNAPL being clearly delineated. Here in Elmira subsurface free phase DNAPL has been found both on the Uniroyal site (OW88 near PW4) as well as off-site by the Howard St. Water Tower (OW57-32 (R). This data should have more than rung the alarm bells thirty-six years ago and precipitated appropriate DNAPL action. Instead it was all Uniroyal hands, friends and fellow travellors (including the M.O.E.) on deck to deny, deflect, delay and manage the situation and crisis. By manage I don't mean investigate proper cleanup as much as investigate improper coverup.